Product ID:A-100* EXTERIOR OIL WOOD PRIMER, WHITE ALKYD PAINT,
NO.:MSDS Date:09/19/1996
FSC:8010
NIIN:00-754-2610
Status Code:A
MSDS Number: CKDXD

SHERWIN-WILLIAMS COMPANY

101 PROSPECT AVENUE
CLEVELAND, OH 44115
US

Emergency Phone: 1-216-566-2917

Info Phone: 216-566-2902

Cage: 54636

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

MINERAL SPIRITS VP= 2.0

CAS: 64742-88-7

OSHA PEL 100 PPM

ACGIH TLV: 100 PPMM

MINERAL SPIRITS 140-FLASH. VP= 0.50

OSHA PEL 100 PPM

ACGIH TLV: 100 PPMM

QUARTZ

CAS: 14808-60-7

RTECS: VV7330000

OSHA PEL 0.1 MG/M3

ACGIH TLV: 0.1 MG/M3

CRYSTOBALITE

CAS: 14464-46-1

RTECS: VV7325000

OSHA PEL 0.05MG/M3

ACGIH TLV: 0.05 MG/M3

TALC

CAS: 14807-96-6

RTECS: WW2710000

OSHA PEL 2MG/M3 (RESP DUST)

ACGIH TLV: 2MG/M3 (RESP DUST)

MICA

CAS: 12001-26-2

RTECS: VV8760000

OSHA PEL 3MG/M3 (RESP DUST)

ACGIH TLV: 3MG/M3 (RESP DUST)

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 10(5MG/M3TOT.DUST)

ACGIH TLV: 10(5MG/M3TOT.DUST)

Health Hazards Acute and Chronic:EXPOSURE MAY BE BUY INHALATION, AND/OR
SKIN OR EYE CONTACT, DEPENDING ON CONDITIONS OF USE. TO MINIMIZE
EXPOSURE, FOLLOW RECOMMENDATIONS FOR PROPER USE, VENTILATION AND
PERSONAL EQUIPMENT. CRYS TALLINE SILICA (QUARTZ,
CRISTOBALITE) IS LISTED BY IARC AND NTP. LONG TERM EXPOSURE TO
HIGH LEVELS OF SILICA DUST, WHICH CAN OCCUR ONLY WHEN SANDING OR
ABRADING THE DRY FILM, MAY CAUSE LUNG DAMAGE (S ILICOSIS) AND
POSSIBLY CANCER. PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS IN
SECTION II MAY CAUSE ADVERSE EFFECTS TO THE LIVER AND URINARY
SYSTEMS.
Effects of Overexposure:IRRITATION OF EYES, SKIN AND RESPIRATORY
SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE
MAY RESULT IN UNCONSCIOUSNESS AND POSSIBLY DEATH. HEADACHE,
DIZZINESS, NAUSEA, AND LOSS OF COORDINATION ARE INDICATIONS OF
EXCESSVE EXPOSURE TO VAPORS OR SPRAY MISTS. REDNESS AND ITCHING OR
BURNING SENSATION MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED

First Aid:INHALED: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE
BREATHING. KEEP WARM AND QUIET. SKIN CONTACT: WASH AFFECTED AREA
THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
LAUNDER BEFORE RE-USE. EYE CONTACT: FLUSH EYES WITH LARGE AMOUNTS
OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: GET
MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:=40.6C, 105.F
105F
Lower Limits:.9
Upper Limits:6
Extinguishing Media:CO2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:FULL PROTECTIVE EQIPMENT INCLUDING SCBA SHOULD
BE USED.WATER SPRAY MAY BE INEFFECTIVE.IF WATER IS USED,FOG NOZZLES
PREFERABLE.WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT
PRESSURE BUILDUP&PO SSIBLE AUTOIGNITION/XPLOSION WH-XPOSED TO
XTREME HEAT.FLAMMABILITY CLASSIFICATION:COMBUSTIBLE,FLASH ABOVE
99&BELOW200F
Unusual Fire/Explosion Hazard:KEEP TIGHTLY CLOSD.ISLATE
F/HEAT,ELECTRICL EQIPMENT,SPRKS,&OPEN FLME.CLOSD CONTAINERS MAY
XPLODE WH-XPOSED-XTREME HEAT.APPLICATION-HOT SURFCES REQUIRES
SPECIAL PRCAUTIONS.DURING EMERGENCY CONDITIONS O
VERXPOSURE-DECOMPSITION PRODUCTS MAY CAUSE HEALTH HAZARD.SYMPTOMS
MAY NOT BE IMMEDIATELY APPARENT.GET MEDICAL ATTENTION.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.

Handling and Storage Precautions:CONTENTS ARE COMBUSTIBLE. KEEP AWAY
FROM HEAT AND OPEN FLAME. CONSULT NFPA CODE. USE APPROVED BONDING
AND GROUNDING PROCEDURES. KEEP CONTAINER CLOSED WHEN NOT IN USE.

Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION,WEAR PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION
AGAINST INGREDIENTS.WH- SANDING/ABRADING DRIED FILM,WEAR DUST/MIST
RESPIRATOR APPROVED BY NIOSH/MSHA FOR DUST WHICH MAY BE GENERATED
FROM PRODUCT,UNDERLYING PAINT,/ABRASIVE.
Ventilation:LOCAL EXHAUST PREFERABLE.GENERAL EXHAUST ACCEPTABLE IF
XPOSURE-INGREDIENTS MAINTAINED BELOW APPLICABLE LIMITS.REFER-OSHA
STANDARDS 1910.94,1910.107,1910.108.
Protective Gloves:GLOVES RECOMMENDED BY GLOVE SUPPLIER FOR PROTECTIONS
AGAINST INGREDIENTS.
Eye Protection:WEAR SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
Work Hygienic Practices:AVOID CONTACT WITH SKIN AND EYES. WASH HANDS
AFTER USING.
Supplemental Safety and Health
USE ONLY WITH ADEQUATE VENTILATION.AVOID BREATHING VAPOR&SPRAY MIST.MAY
CONTAIN MATERIALS CLASSIFIED AS NUISANCE DUSTS ARE LISTED IN THE
INGREDIENTS, THE APPLICABLE LIMITS FOR NUISANCE DUSTS ARE ACGIH
TLV 10MG/M3 (TOTAL DUST), 3 MG/M3 (RESPIRABLE FRACTION), OSHA PEL
15MG/M3 (TOTAL DUST), 5MG/M3 (RESPIRABLE FRACTION).

Boiling Pt:>148.9C, 300.F
B.P. Text:300-416F
Vapor Density:>AIR
Spec Gravity:1.38
VOC Grams/Liter:2.72
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:42

Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:BY FIRE: CO2, CO

Waste Disposal Methods:WASTE MAY BE HAZARDOUS AS DEFINED UNDERRESOURCE
CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261. WASTE MUST BE
TESTED FOR IGNITABILITY TO DETERMINE APPLICABLE EPA HAZARDOUS WASTE
NUMBERS. INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE
CLOSED CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE
AND LOCAL REGULATIONS REGARDING POLLUTION.

Toxicological Information:RATS EXPOSED TO TITANIUM DIOXIDE DUST AT
250MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOSURE LEVELS ARE
NOT ATTAINABLE IN THE WORKPLACE. REPORTS HAVE ASSOCIATED REPEATED
AND PROLONGED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND
NERVOUS SYSTEM DAMAGE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

SARA Title III Information:NO INGREDIENTS IN THIS PRODUCT AR SUBJECT TO
SARA 313 (40CFR 372.65C)
State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING! THIS
PRODUCT CONTAINS A CHEMICAL KNONW TO THE STATE OF CALIFORNIA TO
CAUSE CANCER. TSCA CERTIFICATION. ALL CHEMICALS IN THIS PRODUCT
ARE LISTED OR ARE EXEMPT FR OM LISTING ON THE TSCA INVENTORY.